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Image Search Results
Journal: Scientific Reports
Article Title: Uncoupled surface spin induced exchange bias in α -MnO 2 nanowires
doi: 10.1038/srep06641
Figure Lengend Snippet: (a), XRD pattern indexed as α -MnO 2 with lattice parameters of a = b = 0.9865 nm and c = 0.2897 nm. The inset shows the square tunnel structure of α -MnO 2 with the space group I 4/ m . The (210) plane is highlighted by the red shaded area. (b), X-ray photoelectron spectroscopy of α -MnO 2 nanowires. Fitted peaks p1 and p2 are responsible for the observed 2P 1/2 peak of Mn 4+ , and fitted peaks p2 and p4 for the 2P 3/2 . The peak splitting of 2P 1/2 and 2P 3/2 comes from the coupling of angular momenta associated with partially filled core and valence shells containing unpaired electrons of Mn 4+ . The orange circle indicates the possible positions of 2P 3/2 for Mn 3+ and Mn 2+ .
Article Snippet: The sample was microstructurally characterized and analysed by X-ray diffraction (XRD: GBCMMA, Cu K α , λ = 0.154056 nm) and Rietveld refinement,
Techniques: Spectroscopy